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When the iron is present as bicarbonate, it acts on soap solutions like the analogous lime and magnesia compounds, producing even worse results. In wool scouring, cotton bleaching, and other processes requiring the use of alkaline carbonates, ferric oxide is precipitated on the fibre.
Professor Moore stood stoutly for the older views, and "believed that he could demonstrate a step which connected inorganic with organic creation." Then he gave an abstruse and highly technical account of a process by which in "solutions of colloidal ferric hydroxide, exposed to strong sunlight," compounds could be formed similar to those to be found in the green plant.
When used, it must not be allowed to remain in the acid solution of ferric chloride for any length of time, since the platinum is attacked and dissolved, and the platinic chloride is later reduced by the stannous chloride, and in the reduced condition reacts with the bichromate, thus introducing an error. Mix ore and flux by thorough stirring with a dry glass rod.
I may also, in the last instance, mention that I have found the above methods of electro-dissolution peculiarly adapted for the preparation of unstable compounds such as stannic nitrate, potassic ferrate, ferric acetate, which are decomposed on the application of heat, and in some instances have succeeded by the following means of crystallizing the resulting compound obtained. Chem. News. Dr.
Third, In the case of an element forming two or more distinct series of compounds, e.g., ferrous and ferric salts, is the transition from one series to another necessarily connected with the addition or subtraction of an even number of hydrogenoid atoms?
As an antidote, the best when the poison is in solution is the hydrated sesquioxide of iron, formed by precipitating tinctura ferri perchloridi with excess of ammonia, or carbonate of soda. This is filtered off through muslin and given in tablespoonful doses. It forms ferric arsenate, which is sparingly soluble. Colloidal iron hydroxide may be used instead.
!Ignition of the Iron Precipitate! Heat a platinum or porcelain crucible, cool it in a desiccator and weigh, repeating until a constant weight is obtained. Fold the top of the filter paper over the moist precipitate of ferric hydroxide and transfer it cautiously to the crucible.
Harrington was assured at the outset by Edison that while the Little perforator would give on the average only seven or eight words per minute, which was not enough for commercial purposes, he could devise one giving fifty or sixty words, and that while the Little solution for the receiving tape cost $15 to $17 per gallon, he could furnish a ferric solution costing only five or six cents per gallon.
Examine and burn a piece of magnesium ribbon, noting the white compound of magnesium oxide which is formed. Iron. Examine pieces of the metal and also some of its compounds, as ferrous sulphate, ferric chloride, and ferric oxide or iron rust. Sodium. Drop a piece of the metal on water and observe results. Sodium decomposes water.
Potassium permanganate oxidizes ferrous salts in cold, acid solution promptly and completely to the ferric condition, while in hot acid solution it also enters into a definite reaction with oxalic acid, by which the latter is oxidized to carbon dioxide and water.
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