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On the same principle that electro-dissolution is used for the estimation of combined carbon in steel, etc., I have lately varied the experiment by introducing, instead of steel, iron containing a certain percentage of boron, and, having connected the respective boride with the positive pole of a powerful battery, and to the negative a plate of platinum, using as a solvent dilute sulphuric acid, I observed, after the lapse of about twelve hours, the iron had entirely passed into solution, and a considerable amount of brownish precipitate had collected at the bottom of the vessel, intercepted by flakes of graphite and carbon; the precipitate, having been collected on a filter paper, washed, and dried, on examination proved to be amorphous boron, containing graphite and other impurities, which had become chemically introduced during the preparation of the boron compound.
I may also, in the last instance, mention that I have found the above methods of electro-dissolution peculiarly adapted for the preparation of unstable compounds such as stannic nitrate, potassic ferrate, ferric acetate, which are decomposed on the application of heat, and in some instances have succeeded by the following means of crystallizing the resulting compound obtained. Chem. News. Dr.
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