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Updated: June 12, 2025
After each application of the nitrate, the plate should be rubbed gently in one direction, with moistened bitartrate of potassa, applied with buff. This coat of silver receives a fine polish from peroxide of iron and buff. Proofs are said to have been taken on it, comparable with those obtained on French plates.
The use of a solution of potassa in the preparation of the plate was suggested in the early history of the Daguerreotype. It was thought to possess some peculiar property for improving the tone of the impression.
The solution may be evaporated to dryness, and one part of the salt dissolved in six of water; one part of muriatic acid, sp. gr. 1.15, is then added, and the solution distilled, when the whole of the hydrocyanic acid passes over, and by being conducted into a solution of potassa, as in the former process, forms cyanuret of potassium.
It is the soda of our bread; the potassa of our ashes; the phosphorus of our bones and brain! Indeed, the universe throughout is of one form and one substance, and there is one Father over all. Sooner or later the concepts of science and of religion will come together; and the small agitations and conflicts of human thought and hope will pass away in a sublime unity of human faith.
That smoke consists of those very particles which are produced by the combustion of the phosphorus. Here, again, are two substances. This is chlorate of potassa, and this other sulphuret of antimony. I shall mix these together a little, and then they may be burnt in many ways.
From the acids in insoluble and a few other compounds, chromic, arsenic, and arsenious acids, by fusion with carbonate of soda in presence of carbonic acid gas; borate of manganese is readily decomposed when the boracic acid is to be determined by boiling with solution of potassa, dissolving the residue in hydrochloric acid and precipitating the manganese as binoxide.
Set the deposit in the sun, or by a stove to dry. When perfectly dry, pulverize, and it is ready for use. With a little trouble you will obtain in this way a much better article than can generally be bought of dealers. For the last washing, alcohol, or a mixture of alcohol and water, is preferable." Potassa Solution.
The sulphocyanide of potassium, KCsy, is prepared by fusing ferrocyanide of potassium, deprived of its water of crystallization, intimately mixed with half its weight of sulphur and 17 parts of carbonate of potassa.
In manufactories where no refining is done, the crude potassa in powder is pushed on to a prolongation of the apparatus which is cooled by means of water, and is removed from time to time with shovels by the workmen, so that the orifice of the boiler remains constantly covered externally by the mass, and that the air cannot re-enter the apparatus.
The wool taken out of the liquid and purified by washing in water and wringing is moistened in a test-tube with pure potassa lye at 10 per cent. It is carefully heated till the wool is completely dissolved, and the solution, when cold, is mixed first with half its volume of pure alcohol, upon which is carefully poured the same volume of ether, and the whole is shaken.
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