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The phenomena of isomerism, or identity of composition and proportions of constituents with difference of qualities, and of isomorphism, or identity of form in crystals which have one element substituted for another, were equally surprises to science; and although the mechanism by which they are brought about can be to a certain extent explained by a reference to the hypothetical atoms of which the elements are constituted, yet this is only turning the difficulty into a fraction with an infinitesimal denominator and an infinite numerator.
Another uniformity is that called the law of isomorphism; the identity of the crystalline forms of substances which possess in common certain peculiarities of chemical composition. Thus it appears that even heteropathic laws, such laws of combined agency as are not compounded of the laws of the separate agencies, are yet, at least in some cases, derived from them according to a fixed principle.
In the same year Eilhard Mitscherlich, a German investigator, observed that compounds having the same number of atoms to the molecule are disposed to form the same angles of crystallization a property which he called isomorphism.
Now, M. De Senarmont has shown that the geometric isomorphism of certain substances does not necessarily involve identity of optical properties, and in particular in the directions of the axes of optical elasticity in relation to the geometric directions of the crystal.
Trap Rocks. Name whence derived. Minerals most abundant in Volcanic Rocks. Similar Minerals in Meteorites. Theory of Isomorphism. Basaltic Rocks. Trachytic Rocks. Special Forms of Structure. The columnar and globular Forms. Trap Dikes and Veins. Alteration of Rocks by volcanic Dikes. Conversion of Chalk into Marble. Intrusion of Trap between Strata.
It is even possible that, as has been already partly effected by Dalton's law of definite proportions, and the law of isomorphism, chemistry itself, which is now the least deductive of sciences, may be made deductive, through the laws of the combinations being ascertained to be, though not compounded of the laws of the separate agencies, yet derived from them according to a fixed principle.
And so as soon as the claims of Dulong and Petit and of Mitscherlich had been substantiated by other observers, the laws of the specific heat of atoms, and of isomorphism, took their place as new levers of chemical science. With the aid of these new tools an impregnable breastwork of facts was soon piled about the atomic theory.
The phenomena of isomorphism showed a relation between the units and crystalline forms; certain units are thus able to replace others in a crystalline body without altering its form, and others are not.
Finally, Isomorphism, or the equality of form of many chemical compounds having a different composition, tends to prove that matter consists of atoms the mere arrangement of which produces all the properties of bodies.
The phenomena of isomerism, or identity of composition and proportions of constituents with difference of qualities, and of isomorphism, or identity of form in crystals which have one element substituted for another, were equally surprises to science; and although the mechanism by which they are brought about can be to a certain extent explained by a reference to the hypothetical atoms of which the elements are constituted, yet this is only turning the difficulty into a fraction with an infinitesimal denominator and an infinite numerator.
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