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Updated: May 29, 2025
This work was drawn up by two travellers: one of whom supplied the statistical remarks, and the other, who traversed Prussia on foot, the remarks on entomology, amber, the sturgeon fishery, and other branches of natural history and economics. Wanderrungen durch Rugen. Von Carl. Nernst. Dusseld. 1801. 8vo.
Extending the analogy, already so happily invoked, between the phenomena met with in solutions and those produced in gases, Professor Nernst supposes that metals tend, as it were, to vaporize when in presence of a liquid. A piece of zinc introduced, for example, into pure water gives birth to a few metallic ions.
Professor Nernst goes further, and has shown that the concentration currents which are produced when two electrodes of the same substance are plunged into two unequally concentrated solutions may be interpreted by the hypothesis that, in these particular conditions, the diffusion does bring about a separation of the ions.
Professor Nernst, who before gave, as has been said, a remarkable interpretation of the diffusion of electrolytes, has, in the direction pointed out by M. Arrhenius, developed a theory of the entire phenomena of electrolysis, which, in particular, furnishes a striking explanation of the mechanism of the production of electromotive force in galvanic batteries.
M. Blondlot, one of the masters of contemporary physics, deeply respected by all who know him, admired by everyone for the penetration of his mind, and the author of works remarkable for the originality and sureness of his method, discovered them in radiations emitted from various sources, such as the sun, an incandescent light, a Nernst lamp, and even bodies previously exposed to the sun's rays.
Developing this idea, Professor Nernst calculates, by means of the action of the osmotic pressures, the variations of energy brought into play and the value of the differences of potential by the contact of the electrodes and electrolytes.
Such are the essential facts of osmosis. We may seek to interpret them and to thoroughly examine the mechanism of the phenomenon; but it must be acknowledged that as regards this point, physicists are not entirely in accord. In the opinion of Professor Nernst, the permeability of semi-permeable membranes is simply due to differences of solubility in one of the substances of the membrane itself.
One side of the question has been specially studied on account of its great practical interest, that is to say, the fact that the relation of the luminous energy to the total amount radiated by a body varies with the nature of this last; and the knowledge of the conditions under which this relation becomes most considerable led to the discovery of incandescent lighting by gas in the Auer-Welsbach mantle, and to the substitution for the carbon thread in the electric light bulb of a filament of osmium or a small rod of magnesium, as in the Nernst lamp.
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