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Updated: May 21, 2025
On the other hand, Priestley found that air "phlogisticated" by combustion or respiration could be "dephlogisticated," or have the properties of pure common air restored to it, by the action of green plants in sunshine.
In the course of his researches, Priestley found that the quantity of common air which can thus become "phlogisticated," amounts to about one-fifth the volume of the whole quantity submitted to experiment.
Such expressions as "dephlogisticated" and "phlogisticated" would obviously have little meaning to a generation who were no longer to believe in the existence of phlogiston. It was appropriate that a revolution in chemical thought should be accompanied by a corresponding revolution in chemical names, and to Lavoisier belongs chiefly the credit of bringing about this revolution.
Thus, air contained in a vessel in which a lighted candle had gone out, or a living animal had breathed until it could breathe no longer, was called "phlogisticated." The same result was supposed to be brought about by the addition of what Priestley called "nitrous gas" to common air.
From these experiments he concludes "that when a mixture of inflammable and dephlogisticated air is exploded, in such proportions that the burnt air is not much phlogisticated, the condensed liquor contains a little acid which is always of the nitrous kind, whatever substance the dephlogisticated air is procured from; but if the proportion be such that the burnt air is almost entirely phlogisticated, the condensed liquor is not at all acid, but seems pure water, without any addition whatever."
"I therefore made another experiment," he says, "with some more of the same air from plants in which the proportion of inflammable air was greater, so that the burnt air was almost completely phlogisticated, its standard being one-tenth. The condensed liquor was then not at all acid, but seemed pure water."
Hence it appeared that common air consists, to the extent of four-fifths of its volume, of air which is already "phlogisticated"; while the other fifth is free from phlogiston, or "dephlogisticated."
The question, therefore, would naturally arise as common air can be wholly phlogisticated by combustion, and converted into a substance which will no longer support combustion, is it possible to get air that shall be less phlogisticated than common air, and consequently support combustion better than common air does?
Now, Priestley says that, in 1774, the possibility of obtaining air less phlogisticated than common air had not occurred to him.
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