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Updated: May 19, 2025


The calcium phosphide is prepared by igniting phosphorus in connection with newly slaked lime made chemically pure by calcination. The condition of the shells when the sulphur is added is not material; but the heat renders them porous and without moisture, so that they will absorb the salt to as great an extent as possible.

From that mortar Armand has shot half a dozen bombs of phosphide of calcium which are hurled far into the darkness. They are so constructed that they float after a short plunge and are ignited on contact by the action of the salt water itself." It was a beautiful pyrotechnic display, lighting up the shore and hills of the bay as if by an unearthly flare.

This mixture is placed in a crucible or retort and heated to a white heat for four or five hours, when it is to be removed and forty parts more of sulphur, one and one-half parts of calcium phosphide, and one-half part of chemically pure sulphide of calcium added. The mixture is then heated for about ninety minutes to an extreme white heat.

The herein described process of manufacturing phosphorescent materials, which consists in heating sea shells red-hot, treating them while heated with a bath of brine, then, after removal from the bath, mixing sulphur and phosphide and sulphide of calcium therewith, and finally subjecting the mixture to a white heat, substantially as and for the purpose described.

The shells thus prepared are used with sulphur and the phosphide and sulphide of calcium to produce a phosphorescent composition, as follows: One hundred parts, by weight, of the shells, prepared as above, are intimately mixed with twenty parts, by weight, of sulphur.

When cold, and after exposure to light, this mixture will become luminous. Instead of these two ignitions, the same object may be in a measure accomplished by the addition of the full amount of sulphur with the phosphide and sulphide of calcium and raising it to a white heat but once.

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