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The arsenic is easily calculated from the quantity of silver nitrate consumed. For very rough determinations it is sufficient to treat ten grms. of finely-ground sulphur with nitric acid, to extract with ammonia, and to add silver nitrate.
Versmann found 14.1 grms. of dried liver to contain 0.009 grm. chloride of silver, or 0.047 per cent. of metallic silver. In the kidneys he found 0.007 grm. chloride of silver, or 0.061 per cent. of metallic silver; this was in a case of chronic poisoning, the percentage will be seen to be very small. Orfila Jun. found silver in the liver five months after the poisoning.
The reagents are solution of mercury iodo-chloride prepared by dissolving of 25 grms. iodine, 500 c.c. alcohol of 95 per cent., and of 30 grms. mercury chloride in an equal measure of the same solvent; both liquids are filtered and united; a standard solution of sodium hyposulphite produced by digestion of 24 grms. of the dry salt with 1 liter water and titration with iodine solution; solution of potassium iodide of 1:10; chloroform, and finally a solution of starch.
For the preparation of iodide of mercury, Dublanc recommends to cover 100 grms. of mercury with 1 kilogrm. of alcohol, to add 124 grms. of iodine gradually in portions of ten grms., and agitating between each fresh addition, until the alcohol becomes colorless again. After the addition of the last 4 grms. the alcohol remains colored, the whole of the mercury having become converted into iodide.
In this way Engelmann was able to determine the evolution of oxygen by Euglena and by chlorophyl granules. By H SCHAEPPI. Ten grms. of sulphur, pulverized as finely as possible, are covered with hot water and a few drops of nitric acid digested for some time, filtered, and washed till the washings have no longer an acid reaction.
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