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Updated: June 8, 2025
M. Natanson, and subsequently P. Curie and M. Meslin, have shown by various considerations that the same result may be arrived at by choosing units which correspond to any corresponding states; it has also been shown that the theorem of corresponding states in no way implies the exactitude of Van der Waals' formula.
The experiments fit in fairly well with the formula of Van der Waals, but considerable discrepancies occur when we extend its limits, particularly when the pressures throughout a rather wider interval are considered; so that other and rather more complex formulas, on which there is no advantage in dwelling, have been proposed, and, in certain cases, better represent the facts.
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