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Updated: May 21, 2025
Clausius was the first to point out how this might be done from a knowledge of the length of free path; and the calculations were made by Loschmidt in Germany and by Lord Kelvin in England, independently. The work is purely mathematical, of course, but the results are regarded as unassailable; indeed, Lord Kelvin speaks of them as being absolutely demonstrative within certain limits of accuracy.
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