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It appeared to coincide with that of a dark line of iron in the solar spectrum, numbered 1,474 on Kirchhoff's scale. But in 1876 Young was able, by the use of greatly increased dispersion, to resolve the Fraunhofer line "1474" into a pair, the more refrangible member of which he considered to be the reversal of the green coronal ray.
The immediate increase of knowledge was not the chief result of Kirchhoff's labours; still more important was the change in the scope and methods of astronomy, which, set on foot in 1852 by the detection of a common period affecting at once the spots on the sun and the magnetism of the earth, was extended and accelerated by the discovery of spectrum analysis.
Convincing evidence as to the true nature of the solar lines was however at length, in the autumn of 1859, brought forward at Heidelburg. Kirchhoff's experimentum crucis in the matter was a very simple one.
If all this be so, then the Homeric period, as regards houses and domestic life, belongs to an age apart, not truly Mycenaean, and still less later Hellenic. This theory is opposed by Sittl, who makes his point by cutting out, as interpolations, whatever passages do not suit his ideas, and do suit Kirchhoff's this is the regular method of Homeric criticism.
Soon after the publication of Kirchhoff's discovery, Professor Stokes, who also, ten years prior to the discovery, had nearly anticipated it, borrowed an illustration from sound, to explain the reciprocity of radiation and absorption. A stretched string responds to aërial vibrations which synchronize with its own.
The light of the nucleus would give us a continuous spectrum, like that of the Drummond light; but having to pass through the photosphere, as Kirchhoff's beam passed through the sodium flame, those rays of the nucleus which the photosphere emit are absorbed, and shaded lines, corresponding to the rays absorbed, occur in the spectrum.
Abolish the solar nucleus, and we should have a spectrum showing a bright line in the place of every dark line of Fraunhofer, just as, in the case of Kirchhoff's second experiment, we should have the bright sodium lines of the flame if the lime-light were withdrawn.
A "reversing layer," or stratum of mixed vapours, glowing, but at a lower temperature than that of the actual solar surface, was an integral part of Kirchhoff's theory of the production of the Fraunhofer lines.
But no general point of view was attained; nor, it may be added, was it by this path attainable. Kirchhoff's map of the solar spectrum, drawn to scale with exquisite accuracy, and printed in three shades of ink to convey the graduated obscurity of the lines, was published in the Transactions of the Berlin Academy for 1861 and 1862.
The probability is overwhelming that all these substances exist in the atmosphere of the sun. Kirchhoff's discovery profoundly modified the conceptions previously entertained regarding the constitution of the sun, leading him to views which, though they may be modified in detail, will, I believe, remain substantially valid to the end of time.
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