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Such expressions as "dephlogisticated" and "phlogisticated" would obviously have little meaning to a generation who were no longer to believe in the existence of phlogiston. It was appropriate that a revolution in chemical thought should be accompanied by a corresponding revolution in chemical names, and to Lavoisier belongs chiefly the credit of bringing about this revolution.
Priestley did not, however, go so far as this; he was content to suppose that in some way, which he did not explain, the process of calcination resulted in the loss of phlogiston by the mercury, and the gain, by the dephlogisticated mercury, of the property of yielding exceedingly pure or dephlogisticated air when it was heated very strongly.
A little later Priestley discovered that "dephlogisticated air... is a principal element in the composition of acids, and may be extracted by means of heat from many substances which contain them.... It is likewise produced by the action of light upon green vegetables; and this seems to be the chief means employed to preserve the purity of the atmosphere."
This globe was well exhausted by an air-pump, and then filled with a mixture of inflammable and dephlogisticated air by shutting the cock, fastening the bent glass tube into its mouth, and letting up the end of it into a glass jar inverted into water and containing a mixture of 19,500 grain measures of dephlogisticated air, and 37,000 of inflammable air; so that, upon opening the cock, some of this mixed air rushed through the bent tube and filled the globe.
As we have seen, Priestley, in 1774, had discovered oxygen, or "dephlogisticated air." Furthermore, he postulated the theory that combustion was not due to any such illusive thing as "phlogiston," since this did not exist, and it seemed to him that the phenomena of combustion heretofore attributed to phlogiston could be explained by the action of the new element oxygen and heat.
As he had obtained his dephlogisticated air by heating the calx of mercury, that is the powder produced by calcining mercury in the air, Priestley was forced to suppose that the calcination of mercury in the air must be a more complex occurrence than merely the expulsion of phlogiston from the mercury: for, if the process consisted only in the expulsion of phlogiston, how could heating what remained produce exceedingly pure ordinary air?
As this new air thus appeared to be completely free from phlogiston, Priestley called it "dephlogisticated air." What was the nature of this air? Priestley's view, in fact, is that atmospheric air is a kind of saltpetre, in which the potash is replaced by some unknown earth.
It would have been hard for the most ingenious person to have wandered farther from the truth than Priestley does in this hypothesis; and, though Lavoisier undoubtedly treated Priestley very ill, and pretended to have discovered dephlogisticated air, or oxygen, as he called it, independently, we can almost forgive him when we reflect how different were the ideas which the great French chemist attached to the body which Priestley discovered.
A month after he hears of Priestley's experiments, he writes Dr. A few days later, he writes to Dr. Priestley: In the deflagration of the inflammable and dephlogisticated airs, the airs unite with violence become red-hot and, on cooling, totally disappear. The only fixed matter which remains is water; and water, light, and heat, are all the products.
Are we not then authorised to conclude that water is composed of dephlogisticated and inflammable air, or phlogiston, deprived of part of their latent heat; and that dephlogisticated, or pure air, is composed of water deprived of its phlogiston, and united to heat and light; and if light be only a modification of heat, or a component part of phlogiston, then pure air consists of water deprived of its phlogiston and of latent heat?
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