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At Rosario there is but little tosca-rock: near this place I first noticed at the edge of the river traces of an underlying formation, which, twenty- five miles higher up in the estancia of Gorodona, consists of a pale yellowish clay, abounding with concretionary cylinders of a ferruginous sandstone.

At the mouth of the Vivoras, the river flows over a pale cavernous tosca-rock, quite like that in the Pampas, and this APPEARED to underlie the crystalline limestone; but the section was not unequivocal like that at P. Gorda.

The quantity of calcareous matter in this formation, especially in those large districts where the whole mass passes into tosca-rock, is very great: I have already remarked on the close resemblance in external and microscopical appearance, between this tosca-rock and the strata at Coquimbo, which have certainly resulted from the decay and attrition of recent shells: I dare not, however, extend this conclusion to the calcareous rocks of the Pampas, more especially as the underlying tertiary strata in western Banda Oriental show that at that period there was a copious emission of carbonate of lime, in connection with volcanic action.

Thirty miles further south, the small quartz-ridge of Tapalguen is fringed on its northern and southern flank, by little, narrow, flat-topped hills of tosca-rock, which stand higher than the surrounding plain.

This later formation, which is certainly the equivalent of that of the Pampas, is well seen in the valleys in the estancia of Berquelo, near Mercedes; it here consists of reddish earth, full of rounded grains of quartz, and with some small concretions of tosca-rock arranged in horizontal lines, so as perfectly to resemble, except in containing a little calcareous matter, the formation in the eastern parts of Banda Oriental, in Entre Rios, and at other places: in this estancia the skeleton of a great Edental quadruped was found.

The pebbles are of considerable size, and are of hard sandstone, and of quartz, like that of the Ventana: there are also a few well-rounded masses of tosca-rock.

Carpenter finds that the harder varieties of tosca-rock, collected chiefly to the south, contain marine spongoid bodies, minute fragments of shells, corals, and Polythalamia; these perhaps may have been drifted inwards by the tides, from the more open parts of the sea.

On the banks of the Carcarana, a few miles distant, the lowest bed visible was pale Pampean mud, with masses of tosca-rock, in one of which I found a much decayed tooth of the Mastodon: above this bed, there was a thin layer almost composed of small concretions of white tosca, out of which I extracted a well preserved, but slightly broken tooth of Toxodon Platensis: above this there was an unusual bed of very soft impure sandstone.

In the long line of cliffs, between fifty and sixty feet in height, called the Barrancas de S. Gregorio, which extend westward of the Rio S. Lucia, the lower half is formed of coarse sand of quartz and feldspar without mica, like that now cast up on the beach near Maldonado; and the upper half of Pampean mud, varying in colour and containing honeycombed veins of soft calcareous matter and small concretions of tosca-rock arranged in lines, and likewise a few pebbles of quartz.

The bottom of the sea, I may remark, to a distance of several miles from the shore, and to a depth of between sixty and one hundred feet, was found by the anchors to be composed of tosca-rock and reddish Pampean mud. Professor Ehrenberg has examined for me specimens of the two lower beds, and finds in them three Polygastrica and six Phytolitharia.