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In some of the jaspery layers, and in some of the black siliceous slaty bands, there were irregular seams of imperfect pitchstone, undoubtedly of metamorphic origin, and other seams of brown, crystalline limestone. Here, also, were masses, externally resembling ill-preserved silicified wood. Fourthly and fifthly: calcareous pseudo-honestone; and a thick stratum concealed by detritus.

When this occurred, a mountain-mass, several thousand feet in thickness was thus composed; the black calcareous shale-rock, however, always included some layers of the pale-yellowish siliceous sandstone, of the red conglomerate, and of the greenish jaspery and pseudo-honestone varieties.

In some parts, these earthy or tufaceous beds pass into jaspery and into beautifully mottled and banded porcelain rocks, which break into splinters, translucent at their edges, hard enough to scratch glass, and fusible into white transparent beads: grains of quartz included in the porcelainous varieties can be seen melting into the surrounding paste.

Between these points and Mercedes on the Rio Negro, there are scarcely any good sections, the road passing over limestone, tosca-rock, calcareous and bright red sandstones, and near the source of the San Salvador over a wide extent of jaspery rocks, with much milky agate, like that in the limestone near San Juan.

The rocks near the coast, and some way inland, do not differ from those described northwards of Valparaiso: we have much greenstone, syenite, feldspathic and jaspery slate, and grauwackes having a basis like that of claystone; there are some large tracts of granite, in which the constituent minerals are sometimes arranged in folia, thus composing an imperfect gneiss.

When examining the agates, the chalcedonic and jaspery rocks, some of the limestones, and even the bright red sandstones, I was forcibly struck with their resemblance to deposits formed in the neighbourhood of volcanic action.

Proceeding in a north-by-east direction to the village of Combarbala, we come to a third escarpment of the porphyritic conglomerate, dipping eastwards, and forming the outer range of the main Cordillera. The lower beds were here more jaspery than usual, and they included some white cherty strata and red sandstones, alternating with purple claystone porphyry.

Thirdly: a thick stratum of fine-grained, red, sedimentary matter, easily fusible into a white glass, like the basis of claystone porphyry; but in parts jaspery, in parts brecciated, and including crystalline specks of carbonate of lime.

This land, probably islands, must have been mainly formed of porphyries, with some mica-slate, whence the quartz was derived, and with some red sandstone and jaspery rocks.

Above these porphyries comes a coarse, arenaceous conglomerate, the lower half white and the upper half of a pink colour, composed chiefly of pebbles of various porphyries, but with some of red sandstone and jaspery rocks. In some of the more arenaceous parts of the conglomerate, there was an oblique or current lamination; a circumstance which I did not elsewhere observe.